Rexx study generally begins with 
http://www.rexxla.org CL
CL keeps a few pointers [
1]. Howard Fosdick nicely profiled [
2] its significance in the world of 
open source as of mid-2005, in light of IBM's release [
3] of Object Rexx.
Howard Fosdick profile is now at
http://web.archive.org/web/20050830062010/http://programming.newsforge.com/programming/05/06/21/154227.shtml
A 
Tk binding for Rexx can be found at: 
http://rexxtk.sourceforge.net
 There have been others ...; this might be the most lively, as of 2004.